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Reaction type Hetero-Diels-Alder with inverse electron demand Hetero-Diels-Alder with inverse electron demand Hetero-Diels-Alder Diels-Alder Diels-Alder Diels-Alder Diels-Alder [2 3]-cycloadditions [2 3]-cycloadditions Support Caroline trading ester Aryl-diisopropylsilyl Diisopropylsilyl ether Wang, BOBA ether, 2-MeO-Wang amide Wang ester Hydroxymethyl polystyrene Merrifield with aliphatic chiral spacer PS-bound Evans caroline trading MerrifieldWang MerrifieldWang Catalyst Eu(fod)3 Yb(OTf )3 MeAlCl2 ZnCl2 TiCl3(OiPr) Et2AlCl Mg(ClO4)2 Sc(OTf )3 Reference a,b-unsaturated carbonyl  a,b-unsaturated carbonyl  [242, 243, 244] [245, 246]    [250.
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